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1.
2.
From the changes in energy band, density of state (DOS) and electronic structure calculated by the DFT/B3LYP method, the conductivity of carbon doped boron‐nitride nanotube (BNNT), which is formed by C‐C bond substituting B‐N bond, was discussed. The results indicate that the substitution will strengthen the conductivity of the tube, and its semi‐conductivity might be adjusted by controlling the substitution. 相似文献
3.
采用动态TG-DTG,研究了铁催化剂的制备方法、前驱化合物的 种类及 热处理对其在碳-氧反应中催化活性的影响。观察到在干混法制备催化剂时,所用铁盐分解温度越低活性越高。此外还发现,热处理可明显提高由分解温度高的含氧铁盐制备的 催化剂的活性,但对于不含氧铁盐和分解温度低的含氧铁盐无影响。 相似文献
4.
IntroductionConsiderableattelltionisno\vbeillgpaidtotheCO7refonningof.etha..llto]forseveralreasonst(l)withthedevelopmentofindustrics.moreandnlorcCOZIsabettedintotheatmosphere,leadingto"greenhouseeffect",whichhasbroughtaboutgreatilltcreslallovertheworld.Th… 相似文献
5.
用~(57)Fe穆斯堡尔谱研究了炭载型复合催化剂中铁化学形态随温度的变化,及各活性组分、助剂对铁化学形态的影响;并通过ESR谱考察了复合催化剂中不同活性组分对铁在载体炭表面电子特性的影响。研究结果表明,复合催化剂中各活性组分、助剂和载体炭与铁之间存在着强相互作用。在350~650℃,载体炭可将铁从Fe_2O_3还原到Fe_3O_4、FeO、α-Fe和生成炭化铁。活性组分Cu和助剂K可改变催化剂中铁周围的电子密度,促进铁在载体炭上从高价态向低价态还原。同时还发现催化剂中Na和Cr对铁有很强的助分散作用。 相似文献
6.
WeiBocheng TangNiansheng WangXueren 《高校应用数学学报(英文版)》2000,15(2):173-183
Abstract. A modified Bates and Watts geometric framework is proposed for quasi-likelihoodnonlinear models in Euclidean inner product space. Based on the modified geometric framework,some asymptotic inference in terms of curvatures for quasi-likelihood nonlinear models is stud-ied. Several previous results for nonlinear regression models and exponential family nonlinearmodels etc. are extended to quasi-likelihood nonlinear models. 相似文献
7.
Polypyrrole (PPy)-cellulose composites were prepared by in situ polymerization of pyrrole in pulp suspension using ferric
chloride as an oxidant. Some sulfonic compounds including p-toluenesulfonic acid and its sodium salt (PTSA and PTSA-Na), benzenesulfonic acid (BSA), dodecylbenzene sulfonic acid and
its sodium salt (DBSA and DBSA-Na), 2-naphthalene sulfonic acid (NSA) and 9,10-anthraquinone-2-sulfonic acid sodium salt (AQSA-Na)
were used as dopants, and their effect on the conductivity of PPy-cellulose composite was investigated. The results showed
that the species and dose of dopants had significant effect on the surface resistivity and environmental stability of PPy-cellulose
composite. As the dopant, PTSA and DBSA had a superior doping effect compared to their sodium salts. The doping result of
BSA was close to that of PTSA. NSA bearing a naphthalene ring and AQSA-Na bearing an anthraquinone ring gave the best conductivity.
Using NSA or AQSA-Na as a dopant, along with suitable polymerization conditions, the PPy-cellulose composite obtained showed
a surface resistivity as low as 20 Ω cm−2. For most dopants, the lowest surface resistivity could be obtained when the molar ratio of dopant to pyrrole was 1:1. Both
ATR-FTIR (attenuated total reflection-Fourier transform infrared spectroscopy) and XPS (X-ray photoelectron spectroscopy)
analysis confirmed that the PPy on pulp fibers doped with PTSA, PTSA-Na, NSA and AQSA-Na had different doping levels. The
higher doping level of the PPy in the composites doped with NAS and AQSA-Na might be related to the stronger interaction of
cellulose with PPy chains. Both SEM (scanning electron microscopy) and AFM (atomic force microscopy) observation revealed
the fine grain microstructure of the PPy on the composites with average grain sizes in the range of 100–200 nm, and the PPy
on the samples doped with NSA and AQSA-Na exhibited quite different morphology as compared to those doped with PTSA and its
sodium salt. 相似文献
8.
The three-dimensional weight function method recently developed by the authors is used to determine stress intensity factors
for two symmetric quarter-elliptical corner cracks at a hole in a wide finite-thickness plate subjected to remote tensile
loading. The geometry parameters considered arer/t=0.5, 1, 2;a/c=0.2, 0.5, 1, 2;a/t=0.2, 0.5 withinc/r=2. The results are compared, where possible, with other solutions available in the literature. Generally good agreement is
observed. The effect of an approximation of the two-dimensional unflawed stress distribution on the accuracy of stress intensity
factors by the weight function method is discussed. 相似文献
9.
Shi Xunqing Wang Zhiping John HL Pang Zhang Xueren Nie Jingxu 《Acta Mechanica Sinica》2002,18(3):274-287
In this study, a new unified creep constitutive relation and a modified energy-based fatigue model have been established respectively
to describe the creep flow and predict the fatigue life of Sn−Pb solders. It is found that the relation successfully elucidates
the creep mechanism related to current constitutive relations. The model can be used to describe the temperature and frequency
dependent low cycle fatigue behavior of the solder. The relation and the model are further employed in part II to develop
the numerical simulation approach for the long-term reliability assessment of the plastic ball grid array (BGA) assembly.
The project supported by the National Natural Science Foundation of China (59705008) 相似文献
10.
Magnesium carbonate whiskers/cellulose fibers hybrid paper was successfully prepared via in situ synthesis process, and the flame retardancy and tensile strength properties were investigated. The effects of magnesium salt type, initial magnesium salt concentration, temperature, time and pH value were also detected. The hybrid paper was characterized by X-ray diffraction, Fourier transform infrared spectroscopy, scanning electron microscopy with energy dispersive X-ray spectroscopy and thermogravimetry-derivative thermogravimetry techniques, respectively. The results showed that the same whiskers/fibers hybrid paper could be prepared from different magnesium salts. If the pH was above 9.4, hydrated basic magnesium carbonate would be created, which would lead to the decrease of oxygen index (OI). Reaction time had no effect on the OI and tensile strength of the hybrid paper. Under the optimized conditions, the OI of the hybrid paper reached 28 %. The in situ synthesis process was much better than the direct addition process. 相似文献